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Herein, we report the synthesis and catalytic application of a new N,N′-dineopentyl-1,2-phenylenediamine-based bismuthenium cation (3).3 has been synthesized via the treatment of chlorobismuthane LBiCl [L = 1,2-C 6 H 4 {N(CH 2 tBu)} 2] (2) with AgSbF 6, and was further used as a robust catalyst for the cyanosilylation of ketones under mild reaction conditions.

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PC Gaming | Xbox App on PC Experience Updates. New Game Pass Sub Navigation Menu Is Now Available for All Players. Back in April, we announced that we had started previewing this new menu with a subset of players. Today, we're excited to share that all PC players can now enjoy these new navigation options inside the Xbox app on PC.

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